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PH传感器的电压是如何转换为pH数值

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zerorobert|  楼主 | 2025-1-10 21:39 | 只看该作者 回帖奖励 |倒序浏览 |阅读模式
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51xlf| | 2025-1-10 22:09 | 只看该作者
/*!
* @file DFRobot_PH.cpp
* @brief Arduino library for Gravity: Analog pH Sensor / Meter Kit V2, SKU: SEN0161-V2
*
* @CopyRight   Copyright (c) 2010 DFRobot Co.Ltd (http://www.dfrobot.com)
* @license     The MIT License (MIT)
* @author [Jiawei Zhang](jiawei.zhang@dfrobot.com)
* @version  V1.0
* @date  2018-11-06
* @url https://github.com/DFRobot/DFRobot_PH
*/


#if ARDUINO >= 100
#include "Arduino.h"
#else
#include "WProgram.h"
#endif

#include "DFRobot_PH.h"
#include <EEPROM.h>

#define EEPROM_write(address, p) {int i = 0; byte *pp = (byte*)&(p);for(; i < sizeof(p); i++) EEPROM.write(address+i, pp);}
#define EEPROM_read(address, p)  {int i = 0; byte *pp = (byte*)&(p);for(; i < sizeof(p); i++) pp=EEPROM.read(address+i);}

#define PHVALUEADDR 0x00    //the start address of the pH calibration parameters stored in the EEPROM

char* DFRobot_PH::strupr(char* str) {
    if (str == NULL) return NULL;
    char *ptr = str;
    while (*ptr != ' ') {
        *ptr = toupper((unsigned char)*ptr);
        ptr++;
    }
    return str;
}

DFRobot_PH::DFRobot_PH()
{
    this->_temperature    = 25.0;
    this->_phValue        = 7.0;
    this->_acidVoltage    = 2032.44;    //buffer solution 4.0 at 25C
    this->_neutralVoltage = 1500.0;     //buffer solution 7.0 at 25C
    this->_voltage        = 1500.0;
}

DFRobot_PH::~DFRobot_PH()
{

}

void DFRobot_PH::begin()
{
    EEPROM_read(PHVALUEADDR, this->_neutralVoltage);  //load the neutral (pH = 7.0)voltage of the pH board from the EEPROM
    //Serial.print("_neutralVoltage:");
    //Serial.println(this->_neutralVoltage);
    if(EEPROM.read(PHVALUEADDR)==0xFF && EEPROM.read(PHVALUEADDR+1)==0xFF && EEPROM.read(PHVALUEADDR+2)==0xFF && EEPROM.read(PHVALUEADDR+3)==0xFF){
        this->_neutralVoltage = 1500.0;  // new EEPROM, write typical voltage
        EEPROM_write(PHVALUEADDR, this->_neutralVoltage);
    }
    EEPROM_read(PHVALUEADDR+4, this->_acidVoltage);//load the acid (pH = 4.0) voltage of the pH board from the EEPROM
    //Serial.print("_acidVoltage:");
    //Serial.println(this->_acidVoltage);
    if(EEPROM.read(PHVALUEADDR+4)==0xFF && EEPROM.read(PHVALUEADDR+5)==0xFF && EEPROM.read(PHVALUEADDR+6)==0xFF && EEPROM.read(PHVALUEADDR+7)==0xFF){
        this->_acidVoltage = 2032.44;  // new EEPROM, write typical voltage
        EEPROM_write(PHVALUEADDR+4, this->_acidVoltage);
    }
}

float DFRobot_PH::readPH(float voltage, float temperature)
{
    float slope = (7.0-4.0)/((this->_neutralVoltage-1500.0)/3.0 - (this->_acidVoltage-1500.0)/3.0);  // two point: (_neutralVoltage,7.0),(_acidVoltage,4.0)
    float intercept =  7.0 - slope*(this->_neutralVoltage-1500.0)/3.0;
    //Serial.print("slope:");
    //Serial.print(slope);
    //Serial.print(",intercept:");
    //Serial.println(intercept);
    this->_phValue = slope*(voltage-1500.0)/3.0+intercept;  //y = k*x + b
    return _phValue;
}


void DFRobot_PH::calibration(float voltage, float temperature,char* cmd)
{
    this->_voltage = voltage;
    this->_temperature = temperature;
    String sCmd = String(cmd);
    sCmd.toUpperCase();
    phCalibration(cmdParse(sCmd.c_str()));  // if received Serial CMD from the serial monitor, enter into the calibration mode
}

void DFRobot_PH::calibration(float voltage, float temperature)
{
    this->_voltage = voltage;
    this->_temperature = temperature;
    if(cmdSerialDataAvailable() > 0){
        phCalibration(cmdParse());  // if received Serial CMD from the serial monitor, enter into the calibration mode
    }
}

boolean DFRobot_PH::cmdSerialDataAvailable()
{
    char cmdReceivedChar;
    static unsigned long cmdReceivedTimeOut = millis();
    while(Serial.available()>0){
        if(millis() - cmdReceivedTimeOut > 500U){
            this->_cmdReceivedBufferIndex = 0;
            memset(this->_cmdReceivedBuffer,0,(ReceivedBufferLength));
        }
        cmdReceivedTimeOut = millis();
        cmdReceivedChar = Serial.read();
        if (cmdReceivedChar == '\n' || this->_cmdReceivedBufferIndex==ReceivedBufferLength-1){
            this->_cmdReceivedBufferIndex = 0;
            strupr(this->_cmdReceivedBuffer);
            return true;
        }else{
            this->_cmdReceivedBuffer[this->_cmdReceivedBufferIndex] = cmdReceivedChar;
            this->_cmdReceivedBufferIndex++;
        }
    }
    return false;
}

byte DFRobot_PH::cmdParse(const char* cmd)
{
    byte modeIndex = 0;
    if(strstr(cmd, "ENTERPH")      != NULL){
        modeIndex = 1;
    }else if(strstr(cmd, "EXITPH") != NULL){
        modeIndex = 3;
    }else if(strstr(cmd, "CALPH")  != NULL){
        modeIndex = 2;
    }
    return modeIndex;
}

byte DFRobot_PH::cmdParse()
{
    byte modeIndex = 0;
    if(strstr(this->_cmdReceivedBuffer, "ENTERPH")      != NULL){
        modeIndex = 1;
    }else if(strstr(this->_cmdReceivedBuffer, "EXITPH") != NULL){
        modeIndex = 3;
    }else if(strstr(this->_cmdReceivedBuffer, "CALPH")  != NULL){
        modeIndex = 2;
    }
    return modeIndex;
}

void DFRobot_PH::phCalibration(byte mode)
{
    char *receivedBufferPtr;
    static boolean phCalibrationFinish  = 0;
    static boolean enterCalibrationFlag = 0;
    switch(mode){
        case 0:
        if(enterCalibrationFlag){
            Serial.println(F(">>>Command Error<<<"));
        }
        break;

        case 1:
        enterCalibrationFlag = 1;
        phCalibrationFinish  = 0;
        Serial.println();
        Serial.println(F(">>>Enter PH Calibration Mode<<<"));
        Serial.println(F(">>>Please put the probe into the 4.0 or 7.0 standard buffer solution<<<"));
        Serial.println();
        break;

        case 2:
        if(enterCalibrationFlag){
            if((this->_voltage>1322)&&(this->_voltage<1678)){        // buffer solution:7.0{
                Serial.println();
                Serial.print(F(">>>Buffer Solution:7.0"));
                this->_neutralVoltage =  this->_voltage;
                Serial.println(F(",Send EXITPH to Save and Exit<<<"));
                Serial.println();
                phCalibrationFinish = 1;
            }else if((this->_voltage>1854)&&(this->_voltage<2210)){  //buffer solution:4.0
                Serial.println();
                Serial.print(F(">>>Buffer Solution:4.0"));
                this->_acidVoltage =  this->_voltage;
                Serial.println(F(",Send EXITPH to Save and Exit<<<"));
                Serial.println();
                phCalibrationFinish = 1;
            }else{
                Serial.println();
                Serial.print(F(">>>Buffer Solution Error Try Again<<<"));
                Serial.println();                                    // not buffer solution or faulty operation
                phCalibrationFinish = 0;
            }
        }
        break;

        case 3:
        if(enterCalibrationFlag){
            Serial.println();
            if(phCalibrationFinish){
                if((this->_voltage>1322)&&(this->_voltage<1678)){

                    EEPROM_write(PHVALUEADDR, this->_neutralVoltage);
                }else if((this->_voltage>1854)&&(this->_voltage<2210)){
                    EEPROM_write(PHVALUEADDR+4, this->_acidVoltage);
                }
                Serial.print(F(">>>Calibration Successful"));
            }else{
                Serial.print(F(">>>Calibration Failed"));
            }
            Serial.println(F(",Exit PH Calibration Mode<<<"));
            Serial.println();
            phCalibrationFinish  = 0;
            enterCalibrationFlag = 0;
        }
        break;
    }
}

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